Solutions and their Classification

Solution is that type of colloidal system which has solid as dispersed phase and liquid as dispersion medium e.g. paints, muddy water etc. Sols may be classified as Lyophilic means liquid living. These are those sols may be classified as Lyophilic and Lyophobic sols.

Lyophilic Solutions:- The word Lyophilic means liquid loving. These are those sols which are formed by limply dissolving the dispersed phase into the dispersion medium. e.g. sols of Gum, starch etc.

Lyophobic Solutions:- The word Lyophobic means liquid – hating. These are the sols which are not formed by simply mixing the dispersion medium and dispersed phase, but some special methods are employed for the preparation of these sols. e.g. sols of metals, their sulphides etc.

Difference between Lyophilic and Lyophobic Sols:-

Property

Lyophilic sol

Lyophobic sol

  1. Ease of preparation

Lyophilic sols are prepared easily by directly mixing the dispersed phase with dispersion medium.

Lyophobic sols can not be prepared directly. They are prepared by special methods.

  1. Stability

These are quite stable and are not easily precipitated or coagulated. They are highly hydrated.

These are easily precipitated by adding suitable electrolytes.

  1. Hydration

They are reversible in nature i.e. once

They are not much hydrated

  1. Reversible and irreversible nature

Precipitated can reform the colloidal solution by simply remixing with dispersion medium

They are irreversible in nature i.e. once precipitated can not from colloidal sol. By simply addition of the dispersion medium

  1. Nature of substances

These are usually formed by the organic substances like starch, gum, proteins etc.

These sols are usually formed by inorganic materials like metals and their sulphides etc.

  1. Viscosity

The viscosity is much higher than medium

The viscosity is almost same as that of medium

  1. Surface tension

The surface tension is usually lower than that of the dispersion medium.

The surface tension is nearly same as that of dispersion medium

  1. Visibility

The particles are neither visible nor detected easily by the ultra microscope.

The particles are through not visible, can be detected by the ultra microscope.

  1. Migration in an electric field.

The particles may migrate in either direction or may not migrate at all.

Their particles migrate in only one particular direction in electric field.

 

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